Orientational isomerisation of guest molecules in equilibrium in a tubular host crystal formed <i>via</i> halogen and hydrogen bonding
Orientational isomerisation of guest molecules in equilibrium in a tubular host crystal formed <i>via</i> halogen and hydrogen bonding
复制标题
通过卤素和氢键形成的管状主体晶体中客体分子的定向异构化处于平衡状态
DOI：
10.1039/d1ce01654g
复制
发表时间：
2022
期刊：
影响因子：
3.1
通讯作者：
Shionoya Mitsuhiko
中科院分区：
文献类型：
--
作者：
Yamashita Yutaro;Tashiro Shohei;Shionoya Mitsuhiko
微调两种不同状态的比例对于控制晶体材料的结构和功能非常重要。在这里，我们报告说，笼形客体分子内的管状主体晶体通过卤素和氢键形成表现出可逆的温度依赖性取向异构化平衡。
Fine-tuning of the ratio of two different states is important in controlling the structures and functions of crystalline materials. Here we report that clathrated guest molecules inside a tubular host crystal formed via halogen and hydrogen bonding exhibit reversible temperature-dependent orientational isomerisation in equilibrium.