Mild and selective oxidation of alcohols to aldehydes and ketones using NaIO4/TEMPO/NaBr system under acidic conditions
Mild and selective oxidation of alcohols to aldehydes and ketones using NaIO4/TEMPO/NaBr system under acidic conditions
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DOI：
10.1016/j.tet.2006.07.022
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发表时间：
2006-09-18
期刊：
影响因子：
2.1
通讯作者：
Wang, Yan-Guang
中科院分区：
文献类型：
--
作者：
Lei, Ming;Hu, Rui-Jun;Wang, Yan-Guang
报道了以NaIO_4为末端氧化剂，TEMPO催化的醇选择性氧化为相应的醛和酮的反应。NaIO 4/克里思/NaBr体系为对碱性条件敏感的醇的氧化提供了一种温和而有效的方法。在此基础上，开发了可回收的离子液体固载化TEMPO催化氧化苯甲醇的反应体系。(c)2006年由Elsevier Ltd.出版
A TEMPO-catalyzed selective oxidation of alcohols to the corresponding aldehydes and ketones using NaIO4 as the terminal oxidant is reported. The NaIO4/TEMPO/NaBr system provides a mild and efficient method for the oxidation of alcohols that are sensitive to basic conditions. Furthermore, the recoverable ionic liquid immobilized TEMPO-catalyzed oxidation of benzyl alcohol in ionic liquid H2O medium is also developed. (c) 2006 Published by Elsevier Ltd.