Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand
Upper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand
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脚对脚连接的双卡维坦的上缘功能化和超分子聚合
DOI：
10.1039/d0cc00933d
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发表时间：
2020
影响因子：
4.9
通讯作者：
Haino Takeharu
中科院分区：
文献类型：
--
作者：
Shimoyama Daisuke;Sekiya Ryo;Haino Takeharu
通过芳香族Finkelstein碘化反应以良好的产率合成了八碘双腔烷。Sonogashira和Suzuki偶联反应的octaiodobiscavitand产生了上边缘官能化的biscavitands，自组装形成超分子聚合物在固态。
An octaiodobiscavitand was synthesized via an aromatic Finkelstein iodination reaction in good yield. Sonogashira and Suzuki coupling reactions of the octaiodobiscavitand gave rise to upper-rim-functionalized biscavitands that self-assembled to form a supramolecular polymer in the solid state.