A Hybrid Electrode of Co(3)O(4)@PPy Core/Shell Nanosheet Arrays for High-Performance Supercapacitors.
A Hybrid Electrode of Co(3)O(4)@PPy Core/Shell Nanosheet Arrays for High-Performance Supercapacitors.
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用于高性能超级电容器的Co3O4@PPy核/壳纳米片阵列混合电极
DOI:
10.1007/s40820-015-0069-x
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发表时间:
2016
影响因子:
26.6
通讯作者:
Hu J
中科院分区:
文献类型:
--
作者:
Yang X;Xu K;Zou R;Hu J
Herein, combining solverthermal route and electrodeposition, we grew unique hybrid nanosheet arrays consisting of Co3O4nanosheet as a core, PPy as a shell. Benefiting from the PPy as conducting polymer improving an electron transport rate as well as synergistic effects from such a core/shell structure, a hybrid electrode made of the Co3O4@PPy core/shell nanosheet arrays exhibits a large areal capacitance of 2.11 F cm−2at the current density of 2 mA cm−2, a ~4-fold enhancement compared with the pristine Co3O4electrode; furthermore, this hybrid electrode also displays good rate capability (~65 % retention of the initial capacitance from 2 to 20 mA cm−2) and superior cycling performance (~85.5 % capacitance retention after 5000 cycles). In addition, the equivalent series resistance value of the Co3O4@PPy hybrid electrode (0.238 Ω) is significantly lower than that of the pristine Co3O4electrode (0.319 Ω). These results imply that the Co3O4@PPy hybrid composites have a potential for fabricating next-generation energy storage and conversion devices.
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