Highly Selective Hydroboration of Terminal Alkenes Catalyzed by a Cobalt Pincer Complex Featuring a Central Reactive N-Heterocyclic Phosphido Fragment
Highly Selective Hydroboration of Terminal Alkenes Catalyzed by a Cobalt Pincer Complex Featuring a Central Reactive N-Heterocyclic Phosphido Fragment
复制标题
DOI：
10.1021/acs.organomet.0c00741
复制
发表时间：
2021-04
期刊：
影响因子：
2.8
通讯作者：
Andrew M. Poitras;Leah K. Oliemuller;G. Hatzis;Christine M. Thomas
中科院分区：
文献类型：
--
作者：
Andrew M. Poitras;Leah K. Oliemuller;G. Hatzis;Christine M. Thomas
介绍了一种钴螯合物（PPClP）CoCl2作为端烯烃与平烷硼烷（HBPin）氢化反应的预催化剂的应用。这些反应在高温下进行得很快。
The application of a cobalt pincer complex, (PPClP)CoCl2, as a precatalyst for the hydroboration of terminal alkenes with pinacolborane (HBPin) is described. The reactions proceed rapidly under mil...