Propyne Oxidation: A Kinetic Modeling Study
Propyne Oxidation: A Kinetic Modeling Study
复制标题
丙炔氧化：动力学模型研究
DOI：
10.1080/00102209008951627
复制
发表时间：
1990
期刊：
影响因子：
--
通讯作者：
J. Boettner
中科院分区：
文献类型：
--
作者：
P. Dagaut;M. Cathonnet;J. Boettner
摘要 使用综合动力学反应机制对丙炔氧化进行了建模，其中包括有关丙炔氧化反应动力学的最新发现。所提出的机制能够重现在我们的高压喷射搅拌反应器和激波管中获得的实验数据，压力范围为1-13 atm，温度范围为950至2000 K，当量比为0.5至2。所提出的丙炔氧化机制能够正确重现激波管中测量的点火延迟时间和我们的喷射搅拌反应器中测量的分子物种浓度。
Abstract Propyne oxidation was modeled using a comprehensive kinetic reaction mechanism including the most recent findings concerning the kinetics of the reactions involved in the oxidation of propyne. The proposed mechanism is able to reproduce experimental data obtained in our high-pressure jet stirred reactor and in shock tube in the pressure range 1-13 atm, for temperatures extending from 950 to 2000 K and equivalence ratios 0.5 to 2. The proposed propyne oxidation mechanism is able to correctly reproduce ignition delay times measured in shock tube and molecular species concentrations measured in our jet stirred reactor.