Homogeneous Catalytic Oxidation of Arenes and a New Synthesis of Vitamin K3
Homogeneous Catalytic Oxidation of Arenes and a New Synthesis of Vitamin K3
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DOI：
10.1002/anie.199424751
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发表时间：
1995-01
影响因子：
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通讯作者：
W. Adam*;Jianhua Lin;C. R. Saha-Möller;W. Herrmann;R. Fischer;J. Correia
中科院分区：
文献类型：
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作者：
W. Adam*;Jianhua Lin;C. R. Saha-Möller;W. Herrmann;R. Fischer;J. Correia
甲基三氧苯（VII）催化过氧化氢氧化2 -甲基萘(1)，得到收率高、区域选择性高的维生素k3(2)。目前采用的用铬酸合成2的工业方法每公斤产品产生18公斤含铬废物。(图。)
Methyltrioxorhenium (VII)‐catalyzed oxidation of 2‐methylnaphthalene (1) with hydrogen peroxide leads to vitamin K 3 (2) in good yield and high regioselectivity. The currently employed industrial synthesis of 2 with chromic acid produces 18 kg of chromium‐containing waste per kg of product.(Figure Presented.)