Synthesis of chiral sultams via palladium-catalyzed intramolecular asymmetric reductive amination.
Synthesis of chiral sultams via palladium-catalyzed intramolecular asymmetric reductive amination.
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DOI：
10.1039/c6cc09493g
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发表时间：
2017-01
影响因子：
4.9
通讯作者：
B. Song;Chang-Bin Yu;Yue Ji;Mu-Wang Chen;Yong‐Gui Zhou
中科院分区：
文献类型：
--
作者：
B. Song;Chang-Bin Yu;Yue Ji;Mu-Wang Chen;Yong‐Gui Zhou
A novel palladium-catalyzed intramolecular reductive amination of ketones with weakly nucleophilic sulfonamides has been developed in the presence of a Brønsted acid, giving a wide range of chiral γ-, δ-, and ε-sultams in high yields and up to 99% of enantioselectivity.
