A comparative study on indoline dye- and ruthenium complex-sensitized hierarchically structured ZnO solar cells

A comparative study on indoline dye- and ruthenium complex-sensitized hierarchically structured ZnO solar cells
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二氢吲哚染料和钌配合物敏化分级结构ZnO太阳能电池的比较研究

DOI:
10.1016/j.elecom.2012.01.001
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发表时间:
2012-03
影响因子:
5.4
通讯作者:
Tao, Xia
Tao, Xia
中科院分区:
工程技术3区
文献类型:
--
作者:
Ren, Yuannv;Zheng, Yan-Zhen;Zhao, Jiaxing;Chen, Jian-Feng;Zhou, Weilie;Tao, Xia

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我们报告的多分散ZnO聚集体的制造和随后的优化作为有效的光电极的染料敏化太阳能电池(DSC)通过控制退火程序。两种染料,无金属吲哚D149和商业钌配合物N719被用作ZnO DSC的敏化剂,其最大效率(η)分别为5.2%和4.5%。同时,还首次对活性面积为2.4cm ~ 2的D149基和N719基单块ZnO DSC进行了技术探索,其η分别达到2.6%和2.4%。基于D149的DSC的η比基于N719的DSC高归因于扩大的光捕获和降低的界面电阻。因此,D149可以被认为是一个更好的敏化剂候选人,应用于低成本的ZnO基DSC。
We report the fabrication of polydisperse ZnO aggregates and subsequent optimization as effective photoelectrodes for dye-sensitized solar cells (DSCs) by controlling the annealing procedures. Two dyes, a metal-free indoline D149 and a commercial ruthenium complex N719 were used as sensitizers of ZnO DSCs with the maximum efficiencies (η) of 5.2% and 4.5%, respectively. The monolithic D149-based and N719-based ZnO DSCs with respective active area of 2.4cm2were also technically explored for the first time, reaching up to the η of 2.6% and 2.4%, respectively. The higher η of D149-based DSCs than N719-based DSCs is ascribed to expanded light harvesting and reduced interface resistance. Therefore, D149 can be considered as a better sensitizer candidate for application in low-cost ZnO based DSCs.
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