Nonporous Titanium-Oxo Molecular Clusters That Reversibly and Selectively Adsorb Carbon Dioxide

Nonporous Titanium-Oxo Molecular Clusters That Reversibly and Selectively Adsorb Carbon Dioxide
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DOI:
10.1021/ic401122u
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发表时间:
2013-09-02
影响因子:
4.6
通讯作者:
Chun, Hyungphil
Chun, Hyungphil
中科院分区:
化学2区
文献类型:
--
作者:
Hong, Keunil;Chun, Hyungphil

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无孔钛(IV)簇支持羧酸配体显示选择性吸附二氧化碳,即使在非晶相。具有永久内孔的环状Ti-8簇也吸附气体,但不是选择性的。
Nonporous titanium(IV) clusters supported by carboxylate ligands show selective sorption of carbon dioxide even in the amorphous phase. A ring type Ti-8 cluster with a permanent inner pore also adsorbs gases, but not selectively.