Synthesis and characterization of a bisadduct of La@C82

Synthesis and characterization of a bisadduct of La@C82
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DOI:
10.1021/ja058390i
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发表时间:
2006-05-10
影响因子:
15
通讯作者:
Nagase, Shigeru
Nagase, Shigeru
中科院分区:
化学1区
文献类型:
--
作者:
Feng, Lai;Tsuchiya, Takahiro;Nagase, Shigeru

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通过Bingel-Hirsch反应合成了La @ C_(82)的双加成物。其结构已通过X射线晶体学分析明确定义。加合物的一对对映体在单晶中形成二聚体。
A bisadduct of La@C82has been synthesized in a good yield by a Bingel−Hirsch reaction. Its structure has been well-defined by X-ray crystallographic analysis. A pair of enantiomers of the adduct form a dimer in the single crystal.