Syntheses, structures and properties of a series of bis(benzimidazole)-based coordination polymers tuned by camphorate and divalent transition metal ions

Syntheses, structures and properties of a series of bis(benzimidazole)-based coordination polymers tuned by camphorate and divalent transition metal ions
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樟脑酸盐和二价过渡金属离子调控的一系列双(苯并咪唑)基配位聚合物的合成、结构和性能

DOI:
10.1016/j.ica.2014.04.038
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发表时间:
2014-08
期刊:
Inorg. Chim. Acta
影响因子:
--
通讯作者:
Xiu-Li Wang
Xiu-Li Wang
中科院分区:
其他
文献类型:
--
作者:
Chun-Hua Gong;Jin-Hui Xie;Ai-Xiang Tian;Xiu-Li Wang

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合成了五种二维金属有机配位聚合物[M(D-cam)(bbbm)][M(L-cam)(bbbm)] [M = Co(1),Ni(2)和Zn(3)],[CuII(OH)(bbbm)(H2O)]2(NO3)2·2 H2O(4)和[CuI(bbbm)2](HCOO)(5)[H2 cam =草酸,bbbbm = 1,1-(1,4-丁二基)双-1H-苯并咪唑],并对其结构进行了表征。配合物1 - 3是同构的,具有基于两种类型的同手性层的三维(3D)超分子结构。化合物4和化合物5均表现出(4,4)层状结构,并分别通过氢键和π-π堆积作用扩展为三维超分子结构。研究了配合物4的磁性、配合物1 - 5的热稳定性和光致发光性能。
Five two-dimensional (2D) metal–organic coordination polymers, [M(D-cam)(bbbm)][M(L-cam)(bbbm)] [M = Co (1), Ni (2) and Zn (3)], [CuII(OH)(bbbm)(H2O)]2(NO3)2·2H2O (4) and [CuI(bbbm)2](HCOO) (5) [H2cam = camphoric acid and bbbm = 1,1-(1,4-butanediyl)bis-1H-benzimidazole], have been hydrothermally synthesized and structurally characterized. Complexes1–3are isostructural and possess three-dimensional (3D) supramolecular architectures based on two types of homochiral layers. Both4and5exhibit (4,4) layer structures, which are extended into 3D supramolecular architectures by hydrogen bonding and π–π stacking interactions, respectively. The magnetic properties of4, as well as the thermostable and photoluminescent properties of1–5have been investigated.
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