Topological polymer chemistry by programmed self-assembly and effective linking chemistry
Topological polymer chemistry by programmed self-assembly and effective linking chemistry
复制标题
DOI：
10.1016/j.eurpolymj.2010.10.020
复制
发表时间：
2011-04
影响因子：
6
通讯作者：
Takuya Yamamoto;Y. Tezuka
中科院分区：
文献类型：
--
作者：
Takuya Yamamoto;Y. Tezuka
综述了拓扑聚合物化学中存在的挑战。我们特别关注了“静电自组装和共价固定（ESA-CF）”过程的最新进展，该过程结合了有效的连接/切割化学，包括复分解过程和炔-叠氮化物点击反应。各种具有特定官能团和前所未有的多环大分子拓扑结构的新型环状聚合物通过结合有趣的合成方案已被实现。
Ongoing challenges in topological polymer chemistry are reviewed. In particular, we focus on recent developments in an “electrostatic self-assembly and covalent fixation (ESA–CF)” process in conjunction with effective linking/cleaving chemistry including a metathesis process and an alkyne–azide click reaction. A variety of novel cyclic polymers having specific functional groups and unprecedented multicyclic macromolecular topologies have been realized by combining intriguing synthetic protocols.