Facile carbon-sulfur bond cleavage in diarylsulfonium ylides: a catalytic sulfur-to-silicon group transfer.
Facile carbon-sulfur bond cleavage in diarylsulfonium ylides: a catalytic sulfur-to-silicon group transfer.
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DOI：
10.1039/c2cc35762c
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发表时间：
2013-04
影响因子：
4.9
通讯作者：
Xueliang Huang;R. Goddard;N. Maulide
中科院分区：
文献类型：
--
作者：
Xueliang Huang;R. Goddard;N. Maulide
本文报道了一种不寻常的非酰基碳-硫键的裂解。在温和条件下，多种钯（II）配合物可催化该反应。初步结果表明，钢轨与金属中心的配位导致了明显的结构变化。
An unusual cleavage of the non-ylidic carbon-sulfur bond of a sulfonium ylide is reported. The reaction can be catalysed by a variety of palladium(II) complexes under mild conditions. Preliminary results show that coordination of the ylide to the metal center results in significant structural changes.