Palladium catalyzed/silver tuned selective mono-/tetra-acetoxylation of o-carboranes via B-H activation
Palladium catalyzed/silver tuned selective mono-/tetra-acetoxylation of o-carboranes via B-H activation
复制标题
钯催化/银调节通过 B-H 活化对邻碳硼烷进行选择性单/四乙酰氧基化
DOI：
10.1039/c6cc06200h
复制
发表时间：
2016-01-01
影响因子：
4.9
通讯作者：
Yang, Junxiao
中科院分区：
文献类型：
--
作者：
Cao, Ke;Xu, Tao-Tao;Yang, Junxiao
A palladium catalyzed/silver tuned selective mono- and tetra-acetoxylation of o-carboranes has been developed, and a series of mono- and tetra-acetoxylated o-carboranes decorated with active groups have been synthesized with moderate to good yields as well as excellent selectivity. A mechanism involving electrophilic palladation and cyclopalladation of the B-H bond was proposed.
