Formation and Spectroscopic Characterization of the PeroxoFeIII-CuII Complex. A Modeling Reaction of the Heme-Cu Site in Cytochrome c Oxidase
Formation and Spectroscopic Characterization of the PeroxoFeIII-CuII Complex. A Modeling Reaction of the Heme-Cu Site in Cytochrome c Oxidase
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PeroxoFeIII-CuII 络合物的形成和光谱表征。
DOI：
10.1246/cl.1998.351
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发表时间：
1998
影响因子：
1.6
通讯作者：
Y. Naruta
中科院分区：
文献类型：
--
作者：
Takaoki Sasaki;N. Nakamura;Y. Naruta
FeIITPP-CuITPA 1与O2在室温下发生氧化反应，生成了独特的过氧配合物FeIITPP（O2）-CuITPA 2。通过电子吸收光谱、ESI-MS、共振拉曼光谱和ESR光谱对配合物进行了表征。
Formation of a unique peroxo complex FeIITPP(O2)-CuITPA 2 was observed in the oxygenated reaction of FeIITPP-CuITPA 1 with O2 at ambient temperature. This complex was characterized by electronic absorption, ESI-MS, resonance Raman, and ESR spectroscopies.