A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes
A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes
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DOI：
10.1039/b607597e
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发表时间：
2006-01-01
影响因子：
4.9
通讯作者：
Roesky, Peter W.
中科院分区：
文献类型：
--
作者：
Dochnahl, Maximilian;Pissarek, Jens-Wolfgang;Roesky, Peter W.
合成了一种新的锌化合物N-环己基-2-（环己基氨基）托泊亚胺锌甲基，[（Cy）（2）ATI] ZnMe（2），并在非活化烯烃的分子内氢胺化反应中显示出比以前报道的均相锌配合物更上级的反应活性。
The new zinc compound N-cyclohexyl-2-(cyclohexylamino) troponiminate zinc methyl, [(Cy)(2)ATI] ZnMe (2), was synthesized and showed a superior reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to previously reported homogeneous zinc complexes.