Tetra-μ-acetato-bis-[(1,3-benzothia-zole)copper(II)](Cu-Cu).
Tetra-μ-acetato-bis-[(1,3-benzothia-zole)copper(II)](Cu-Cu).
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四-μ-乙酰基-双-[(1,3-苯并噻唑)铜(II)](Cu-Cu)。
DOI：
10.1107/s1600536811027140
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发表时间：
2011
期刊：
影响因子：
--
通讯作者：
Meyer,Gerd
中科院分区：
文献类型：
--
作者：
Hermle,Johannes;Meyer,Gerd
The title compound, [Cu2(CH3CO2)4(C7H5NS)2] or [(C7H5NS)Cu]2(μ-O2CCH3)4, crystallizes with one molecule per unit cell. The coordination number of copper is six with four basal O atoms, one axial N atom and one axial Cu atom. Four acetate ligands act as bidentate linker and connect two Cu atoms, with a crystallographic inversion center located at the mid-point of the Cu—Cu bond. The acetate ligands form slightly distorted square planes around each metal ion, while the copper ions are displaced by 0.2089 (4) Å from these planes towards the N atoms. Thus, the Cu—Cu distance is elongated to 2.6378 (7) Å, compared with the 2.2180 (7) Å distance between the two basal planes. The angle between the basal plane and the Cu—N bond is 4.84 (6)°.
