Allosteric cooperativity in ternary complexes with low symmetry
Allosteric cooperativity in ternary complexes with low symmetry
复制标题
低对称性三元配合物中的变构协同性
DOI：
10.1039/c8cc04195d
复制
发表时间：
2018-07-14
影响因子：
4.9
通讯作者：
Jiang, Wei
中科院分区：
文献类型：
--
作者：
Chai, Hongxin;Yang, Liu-Pan;Jiang, Wei
合成并表征了两种新的含酯基的萘并呋喃酮。以酯型和醚型萘并管的顺式异构体为配体，在一个客体上具有两种不同主体的三元配合物中实现了强的正向别构协同效应。这为构建具有高复杂性和多样性的强大超分子结构铺平了道路。
Two new naphthotubes with ester linkers were synthesized and characterized. With the syn isomers of an ester naphthotube and an ether naphthotube, strong positive allosteric cooperativity in a ternary complex with two different hosts on one guest was achieved. This paves the way to construct robust supramolecular architectures with high complexity and diversity.