CFD and kinetic modelling study of methane MILD combustion in O-2/N-2, O-2/CO2 and O-2/H2O atmospheres
CFD and kinetic modelling study of methane MILD combustion in O-2/N-2, O-2/CO2 and O-2/H2O atmospheres
复制标题
O-2/N-2、O-2/CO2 和 O-2/H2O 气氛中甲烷 MILD 燃烧的 CFD 和动力学模型研究
DOI：
10.1016/j.apenergy.2019.02.046
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发表时间：
2019
期刊：
影响因子：
11.2
通讯作者：
Liu Hao
中科院分区：
文献类型：
--
作者：
Tu Yaojie;Xu Mingchen;Zhou Dezhi;Wang Qingxiang;Yang Wenming;Liu Hao
To deepen the understanding of combining moderate or intense low-oxygen dilution (MILD) combustion with oxy-fuel combustion for enhancing flame stability while realizing carbon capturing and storage, this paper presents a numerical study of methane MILD combustion in three atmospheres, i.e.: O2/N2, O2/CO2and O2/H2O, with both computational fluid dynamics (CFD) and kinetic calculation approaches. Firstly, CFD predictions for the three conditions were performed following a systematic validation of the numerical method against experimental measurement from methane/air MILD combustion in a laboratory-scale closed furnace. Subsequently, kinetic calculations with a well-stirred reactor model was used to quantitatively identify the operating ranges of MILD combustion in the three atmospheres for methane. Moreover, the kinetic calculation provided additional insight into the fuel oxidation pathway. The results reveal that replacing N2with either CO2or H2O would help to establish MILD combustion mode from the viewpoint of lower temperature increase, due to both physical and chemical property discrepancies among the diluents. Specifically, the chemical effect and physical effect are responsible to the lower temperature rise for CO2-diluted case and H2O-diluted case, respectively. Inside the MILD combustion furnace, the negative heat release region disappears in regardless of atmospheres, indicating the eliminated fuel pyrolysis process under MILD combustion mode. Detailed analysis of the flame structure suggests that the combustion regimes inside the furnace in the three atmospheres are all in well-stirred combustion regime, and CO2-diluted case has the most extended reaction zone. Kinetic calculation indicates that CO2or H2O dilution would result in a wider MILD combustion operating range compared to N2dilution, while it is more pronounced for CO2. These observations all imply that MILD combustion will be more easily established with CO2dilution than N2or H2O dilution. However, higher CO formation is obtained in O2/CO2, forcing more attention to be paid on CO emission under CO2-diluted MILD combustion. Furthermore, the hydrocarbon recombination route is negligible under MILD combustion in spite of the atmospheres, implying lower sooting tendency as compared with conventional combustion.
