Copper-catalyzed oxidative desulfurization-oxygenation of thiocarbonyl compounds using molecular oxygen: an efficient method for the preparation of oxygen isotopically labeled carbonyl compounds
Copper-catalyzed oxidative desulfurization-oxygenation of thiocarbonyl compounds using molecular oxygen: an efficient method for the preparation of oxygen isotopically labeled carbonyl compounds
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DOI：
10.1039/b701048f
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发表时间：
2007-01-01
影响因子：
4.9
通讯作者：
Murai, Toshiaki
中科院分区：
文献类型：
--
作者：
Shibahara, Fumitoshi;Suenami, Aiko;Murai, Toshiaki
本文提出了一种新的铜催化硫羰基化合物氧化脱硫反应，利用分子氧作为氧化剂生成羰基化合物，并通过制备羰基o -18标记唾液酸衍生物证明了该工艺的实用性。
A novel copper-catalyzed oxidative desulfurization reaction of thiocarbonyl compounds, using molecular oxygen as an oxidant and leading to formation of carbonyl compounds, has been developed, and the utility of the process is demonstrated by its application to the preparation of a carbonyl-O-18 labeled sialic acid derivative.