Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate.
Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate.
复制标题
通过络合甲酸盐的去质子化和脱羰基化合成四配位钛（IV）氧阴离子。
作者：
Arjun Mendiratta;Joshua S. Figueroa;C. Cummins
甲酸钛配合物[Ar（t-Bu）N] 3 TiOC（O）H与LiN（i-Pr）2的去质子化导致游离CO的释放和钛（IV）含氧阴离子配合物的形成，分离为其锂盐。
Deprotonation of the titanium formate complex [Ar(t-Bu)N]3TiOC(O)H with LiN(i-Pr)2 resulted in the release of free CO and the formation of a titanium(IV) oxoanion complex, isolated as its lithium salt.