Electrochemical reduction of an imidazolium cation: a convenient preparation of imidazol-2-ylidenes and their observation in an ionic liquid
Electrochemical reduction of an imidazolium cation: a convenient preparation of imidazol-2-ylidenes and their observation in an ionic liquid
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DOI：
10.1039/b407386j
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发表时间：
2004-01-01
影响因子：
4.9
通讯作者：
Clyburne, JAC
中科院分区：
文献类型：
--
作者：
Gorodetsky, B;Ramnial, T;Clyburne, JAC
1，3-二(2，4，6-三甲基苯基)咪唑氯化物通过电化学和化学还原生成亲核的卡宾，即1，3-二(2，4，6-三甲基苯基)咪唑-2-亚甲基。卡宾也被证明与离子液体十四基(三己基)氯化膦相容并持续存在。
1,3-Bis(2,4,6-trimethylphenyl) imidazolium chloride is reduced electrochemically and chemically to produce a nucleophilic carbene, namely 1,3-bis(2,4,6-trimethylphenyl) imidazol-2-ylidene. The carbene was also shown to be compatible with and persistent in the ionic liquid tetradecyl(trihexyl) phosphonium chloride.