Amidation of Aryl Halides Catalyzed by the Efficient and Recyclable Cu2O Nanoparticles

Amidation of Aryl Halides Catalyzed by the Efficient and Recyclable Cu2O Nanoparticles
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DOI:
10.1002/cjoc.201090374
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发表时间:
2010-11
影响因子:
5.4
通讯作者:
Zijian Yao;Xian‐Wen Wei
Zijian Yao;Xian‐Wen Wei
中科院分区:
化学2区
文献类型:
--
作者:
Zijian Yao;Xian‐Wen Wei

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结果表明,纳米Cu 2 O/N,N′-二甲基乙二胺(DMEDA)催化体系在温和条件下可有效催化卤代芳烃的酰胺化反应。该方法具有良好的选择性,催化剂可循环使用而不损失活性。该方法具有成本低、操作简单、产率高等优点,适合于工业化生产。
Cu2O nanoparticles/DMEDA (N,N′-dimethylethylenediamine) was proved to be an efficient catalyst system for amidation of aryl halides under mild condition. This method displayed excellent selectivity and the catalyst was recyclable without loss of activity. The low cost, simple operation and excellent yields make this approach attractive for industrial applications.