Selective hydrogenolysis of carbon-oxygen bonds with formic acid over a Au-Pt alloy catalyst
Selective hydrogenolysis of carbon-oxygen bonds with formic acid over a Au-Pt alloy catalyst
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Au-Pt 合金催化剂上甲酸选择性氢解碳氧键
DOI：
10.1039/c6cc09599b
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发表时间：
2017
影响因子：
4.9
通讯作者：
Xiao Feng-Shou
中科院分区：
文献类型：
--
作者：
Wang Liang;Zhang Jian;Wang Guoxiong;Zhang Wei;Wang Chengtao;Bian Chaoqun;Xiao Feng-Shou
我们报道了用生物质衍生的甲酸作为氢源，在CeO2负载的Au-Pt合金催化剂（Au-Pt /CeO2）上进行碳氧选择性氢解。该反应的成功可以合理地归因于Au-Pt /CeO2在甲酸脱氢和碳-氧氢脱氧串联步骤中的高效率。
We reported selective hydrogenolysis of carbon–oxygen species over a CeO2-supported Au–Pt alloy catalyst (Au–Pt/CeO2) using biomass-derived formic acid as the hydrogen source. The success of this reaction is reasonably attributed to the high efficiency of Au–Pt/CeO2 in the tandem steps of formic acid dehydrogenation and carbon–oxygen species hydrodeoxygenation.