Synthesis of N-Sulfonyl Arylaldimines Developed by Retesting an Old Process

Synthesis of N-Sulfonyl Arylaldimines Developed by Retesting an Old Process
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通过重新测试旧工艺开发 N-磺酰芳基醛亚胺的合成

DOI:
10.1021/acs.orglett.5b03686
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发表时间:
2016-02-05
期刊:
影响因子:
5.2
通讯作者:
Hu, Yuefei
Hu, Yuefei
中科院分区:
化学1区
文献类型:
--
作者:
Huang, Dayun;Wang, Xuesong;Hu, Yuefei

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By simply heating the mixture of an arylaldehyde and a sulfonylisocyanate in a solvent or in neat form under catalyst- and additive-free conditions, the desired N-sulfonylimine was produced with the release of carbon dioxide. The method is characterized by its unique clean efficiency, convenience, and scalability, but it was reported to fail half a century ago.