meso-aryl expanded porphyrins: synthesis, structures, and coordination chemistry
meso-aryl expanded porphyrins: synthesis, structures, and coordination chemistry
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DOI：
10.1142/s1088424604000167
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发表时间：
2004
影响因子：
1.5
通讯作者：
Soji Shimizu;A. Osuka
中科院分区：
文献类型：
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作者：
Soji Shimizu;A. Osuka
在改进的Rothemund-Lindsey反应条件下，通过我们的合成方法合成了meso-芳基卟啉，它们可以被认为是meso-四芳基卟啉的真实的同系物。这类新的分子表现出有趣的光谱，电化学和配位性能。这些有前途的功能强调，特别注意的annulenic属性。
meso-aryl expanded porphyrins, that can be regarded as real homologues of meso-tetraaryl porphyrins, were prepared by our synthetic protocol under the modified Rothemund-Lindsey conditions. This new class of molecules exhibits interesting spectral, electrochemical, and coordination properties. These promising features are emphasized, with a particular attention on the annulenic properties.