SRN1 REACTIONS OF A TETRASUBSTITUTED-1,4-BENZOQUINONE
SRN1 REACTIONS OF A TETRASUBSTITUTED-1,4-BENZOQUINONE
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DOI：
10.1016/s0040-4039(00)79881-9
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发表时间：
1991-08-12
影响因子：
1.8
通讯作者：
BARREAU, M
中科院分区：
文献类型：
--
作者：
CROZET, MP;GIRAUD, L;BARREAU, M
The C-alkylation reaction of 2-chloromethyl-3,5,6-trimethyl-1,4-benzoquinone by 2-nitropropane anion is shown to proceed by the S(RN)1 mechanism. This mechanism is confirmed by the inhibitory effects of dioxygen, p-dinitrobenzene, cupric chloride and di-tert-butylnitroxide. The dioxygen-induced formation of nitro and nitrite derivatives is found for the first time.
