Synthesis of Microcrystalline Ce2O3 and Formation of Solid Solutions between Cerium and Lanthanum Oxides

Synthesis of Microcrystalline Ce2O3 and Formation of Solid Solutions between Cerium and Lanthanum Oxides
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DOI:
10.1002/zaac.201300663
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发表时间:
2014-05-01
影响因子:
1.4
通讯作者:
Albert, Barbara
Albert, Barbara
中科院分区:
化学4区
文献类型:
--
作者:
Hamm, Christin M.;Alff, Lambert;Albert, Barbara

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研究了以CeO2和Ce为原料制备金黄色微晶气敏单相氧化铈(Ce2O3)的新方法。合成了CeO2-La2O3体系中的固溶体(Ce1-xLax)O2-0.5x (0 < x < 0.55)和Ce2O3-La2O3体系中的固溶体(Ce1-xLax)(2)O-3 (0 < x < 1),并用x射线粉末衍射方法对其进行了研究。
A new method of preparation of golden-yellow, microcrystalline, and air-sensitive single-phase cerium(III) oxide, Ce2O3, from CeO2 and Ce was developed. Solid solutions (Ce1-xLax)O2-0.5x (0 < x < 0.55) in the system CeO2-La2O3 and (Ce1-xLax)(2)O-3 (0 < x < 1) in the system Ce2O3-La2O3 were synthesized and investigated by means of X-ray powder diffraction.