Thermal cycling and ageing of a glass-ceramic sealant for planar SOFCs

Thermal cycling and ageing of a glass-ceramic sealant for planar SOFCs
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DOI:
10.1016/j.ijhydene.2011.04.083
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发表时间:
2011-09
影响因子:
7.2
通讯作者:
F. Smeacetto;A. Chrysanthou;M. Salvo;T. Moskalewicz;F. D. Bytner;L. C. Ajitdoss;M. Ferraris
F. Smeacetto;A. Chrysanthou;M. Salvo;T. Moskalewicz;F. D. Bytner;L. C. Ajitdoss;M. Ferraris
中科院分区:
工程技术2区
文献类型:
--
作者:
F. Smeacetto;A. Chrysanthou;M. Salvo;T. Moskalewicz;F. D. Bytner;L. C. Ajitdoss;M. Ferraris

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在800℃的SOFC工作温度下,对Crofer22APU/玻璃陶瓷/阳极负载电解质(ASE)加入样品在空气中进行热循环和热老化测试。对Crofer22APU进行抛光处理,并在900℃下预氧化2小时。研究了两个界面的扩散行为,发现铬和锰从Crofer22APU扩散到玻璃陶瓷中。在Crofer22APU/玻璃-陶瓷界面以及玻璃-陶瓷与YSZ之间没有观察到相互作用、破坏或裂纹形成。
Thermal cycling and thermal ageing tests were performed on Crofer22APU/glass-ceramic/Anode-Supported-Electrolyte (ASE) joined samples in air at the SOFC operating temperature of 800 °C. The Crofer22APU had been polished and preoxidised at 900 °C for 2 h. The diffusion behaviour at the two interfaces was examined and revealed slight diffusion of chromium and manganese from Crofer22APU into the glass-ceramic. No interactions, failure or crack formation were observed at the Crofer22APU/glass-ceramic interface and between the glass-ceramic and YSZ.