Nickel-Catalyzed Denitrated Coupling Reaction of Nitroalkenes with Aliphatic and Aromatic Alkenes
Nickel-Catalyzed Denitrated Coupling Reaction of Nitroalkenes with Aliphatic and Aromatic Alkenes
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镍催化硝基烯烃与脂肪族和芳香族烯烃的脱硝偶联反应
DOI：
10.1002/adsc.201600586
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发表时间：
2016
影响因子：
5.4
通讯作者：
Wang Xi-Cun
中科院分区：
文献类型：
--
作者：
Zhang Na;Quan Zheng-Jun;Wang Xi-Cun
以镍为催化剂，三乙氧基硅烷[(ETO)3SiH]为还原剂，实现了一种简单实用的硝基烯烃与多种烯烃的脱硝化偶联反应。在温和的反应条件下，脂肪族和芳香族烯烃都可以在空气气氛下与硝基烯烃反应，得到一系列不同官能团的烯烃，这些以前很难或不可能获得的烯烃。
A simple and practical denitrated coupling reaction of nitroalkenes with various alkenes using a nickel catalyst and triethoxysilane [(EtO)3SiH] as reducing agent was achieved. Under mild reaction conditions, both aliphatic and aromatic alkenes could react with nitroalkenes to obtain a series of olefins with different functional groups in satisfactory yields under an air atmosphere, which were previously difficult or impossible to access.