MASS SPECTROMETRY OF ARYL AZIDES
MASS SPECTROMETRY OF ARYL AZIDES
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DOI：
10.1021/jo00823a030
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发表时间：
1971-01-01
影响因子：
3.6
通讯作者：
SCRIVEN, EFV
中科院分区：
文献类型：
--
作者：
ABRAMOVITCH, RA;KYBA, EP;SCRIVEN, EFV
报道了 18 种单取代的（Cl、CN、NO 2 、MeO、Ph、Me）和两种二取代的苯基叠氮化物的质谱。发现八种叠氮化物的碎片符合所描述的一般或“正常”模式。相对于“正常”碎片描述和讨论了其他叠氮化物的碎片模式，并在许多情况下通过精确的质量测定得到支持。特别讨论了三种甲苯基叠氮化物的质谱，并得到精确质量测定和邻甲苯基叠氮化物-a-15 34C 低分辨率光谱的部分分析的支持。
The mass spectra of 18 monosubstituted (Cl, CN, N02, MeO, Ph, Me) and two disubstituted phenyl azides are reported. The fragmentations of eight of the azides were found to fit a general or “normal” pattern, which is described. Thefragmentation patterns of the other azides are described and discussed with respect to the “normal” fragmentations, supported in a number of cases with accurate mass determinations. The mass spec-tra of the three tolyl azides are discussed in particular, supported by accurate mass determinations and by a partial analysis of the low-resolution spectrum of o-tolyl azide-a-15 34C.