Isolation of a stable 1-iridabicyclo[3.2.0]hepta-1,3,6-triene and its reversible transformation into an iridacycloheptatriene.

Isolation of a stable 1-iridabicyclo[3.2.0]hepta-1,3,6-triene and its reversible transformation into an iridacycloheptatriene.
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DOI:
10.1021/ja0393527
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发表时间:
2004-01
影响因子:
15
通讯作者:
M. Paneque;M. L. Poveda;N. Rendón;K. Mereiter
M. Paneque;M. L. Poveda;N. Rendón;K. Mereiter
中科院分区:
化学1区
文献类型:
--
作者:
M. Paneque;M. L. Poveda;N. Rendón;K. Mereiter

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环烯环戊二烯配合物2与2-丁炔反应,平衡生成环烯环庚三烯3和新型1-环烯环[3.2.0]庚-1,3,6-三烯,4的混合物。
Reaction of the iridacyclopentadiene complex 2 with 2-butyne yields a mixture in equilibrium of the iridacycloheptatriene 3 and a novel 1-iridabicyclo[3.2.0]hepta-1,3,6-triene, 4.