The thermal decomposition of azonitrile polymers
The thermal decomposition of azonitrile polymers
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偶氮腈聚合物的热分解
DOI：
10.1002/macp.1967.021030134
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发表时间：
1967
影响因子：
2.5
通讯作者：
D. A. Smith
中科院分区：
文献类型：
--
作者：
D. A. Smith
在偶氮腈类化合物的均裂反应中，自由基结合的程度通常在50-80摩尔之间。这一现象归因于笼状效应1），其中溶剂分子抑制自由基的扩散，使得结合变得更可能。在本工作中，偶氮腈缩合聚合物含有单元I已制备和热分解。以这种方式
In the homolytic decomposition of azonitrile compounds, the extent of radical combination is often in the range of 50-80 yo. This phenomenon is attributed to the,, cagebL effect1), in which solvent molecules restrain the diffusion of radicals, so that combination becomes more probable. In the present work, azonitrile condensation polymers containing the unit I have been prepared and thermally decomposed. In this way the