Construction of a square-planar hydroperoxo-copper(II) complex inducing a higher catalytic reactivity
Construction of a square-planar hydroperoxo-copper(II) complex inducing a higher catalytic reactivity
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DOI：
10.1039/b308073k
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发表时间：
2003-11-07
影响因子：
4.9
通讯作者：
Masuda, H
中科院分区：
文献类型：
--
作者：
Fujii, T;Naito, A;Masuda, H
制备了一种具有方形平面几何形状的新型氢过氧铜(II)络合物，与三角双锥络合物相比，该络合物对二甲基硫醚表现出更高的选择性和催化反应活性。
A novel hydroperoxo-copper(II) complex with a square-planar geometry has been prepared, which has exhibited a higher selectivity and catalytic reactivity for dimethyl sulfide, in contrast to that with a trigonal-bipyramidal one.