Room temperature, solventless telomerization of isoprene with alcohols using (N-heterocyclic carbene)-palladium catalysts
Room temperature, solventless telomerization of isoprene with alcohols using (N-heterocyclic carbene)-palladium catalysts
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使用（N-杂环卡宾）-钯催化剂进行异戊二烯与醇的室温无溶剂调聚
DOI：
10.1039/c5cy00058k
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发表时间：
2015
影响因子：
5
通讯作者：
Maluenda I
中科院分区：
文献类型：
--
作者：
Maluenda I
介绍了在绿色条件下，使用定制的钯配合物进行异戊二烯与醇的调聚反应。使用非常低的催化剂负载（0.1摩尔%），该方案允许在不需要高压设备的情况下在室温和无溶剂条件下进行反应，从而提供高收率的调聚产物，对线性头对头和尾对头调聚物具有高选择性。
The use of a custom-made palladium complex for the telomerisation of isoprene with alcohols under green conditions is described. Using a very low catalyst loading (0.1 mol%), this protocol allows for the reactions to be carried out without the need of high pressure equipment, at room temperature and under solventless conditions, affording high yields of telomerization products with high selectivity towards linear head-to-head and tail-to-head telomers.