Early-late heterobimetallic complexes as initiator for ethylene polymerization. Cooperative effect of two metal centers to afford highly branched polyethylene.

Early-late heterobimetallic complexes as initiator for ethylene polymerization. Cooperative effect of two metal centers to afford highly branched polyethylene.
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DOI:
10.1039/b605800k
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发表时间:
2006-09
影响因子:
4.9
通讯作者:
J. Kuwabara;Daisuke Takeuchi;K. Osakada
J. Kuwabara;Daisuke Takeuchi;K. Osakada
中科院分区:
化学2区
文献类型:
--
作者:
J. Kuwabara;Daisuke Takeuchi;K. Osakada

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由早-晚过渡金属络合物引发的乙烯聚合可得到支化结构和性质不同的聚合物,这取决于晚过渡金属的类型。
Ethylene polymerization initiated by early-late transition-metal complexes afforded a polymer with different branched structures and properties depending on the type of late transition-metal.