Highly stable olefin-Cu(I) coordination oligomers and polymers.
Highly stable olefin-Cu(I) coordination oligomers and polymers.
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DOI：
10.1039/b407253g
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发表时间：
2005-02
影响因子：
46.2
通讯作者：
Qiong Ye;Xi-Sen Wang;Hong Zhao;R. Xiong
中科院分区：
文献类型：
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作者：
Qiong Ye;Xi-Sen Wang;Hong Zhao;R. Xiong
近年来，高稳定性的Cu(I)-烯烃配位低聚物和聚合物被成功地制备出来，并应用于构建具有有趣物理和化学功能的金属有机骨架（MOFs）。本文综述了烯烃- cu (I)配位低聚物和聚合物及其新的物理性质。从结构到功能，特别强调烯烃- cu (I)配位低聚物和聚合物的配位和有机金属化学，它们的结构和潜在的应用作为固体具有不同寻常的物理功能特性，如电化学，手性分离，荧光传感和铁电性。
Highly stable Cu(I)-olefin coordination oligomers and polymers have been successfully prepared and applied to construct metal-organic frameworks (MOFs) with interesting physical and chemical functions in recent years. In this review, we present the olefin-Cu(I) coordination oligomers and polymers and their novel physical properties. From structure to functions, particular emphasis is placed on the coordination and organometallic chemistry of olefin-Cu(I) coordination oligomers and polymers, their structures and potential applications as solids possessing unusual physical functional properties such as electrochemical, chiral separation, fluorescent sensing and ferroelectricity.