Temperature and humidity compensation in the determination of solvent vapors with a microsensor system.

Temperature and humidity compensation in the determination of solvent vapors with a microsensor system.
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使用微传感器系统测定溶剂蒸气时的温度和湿度补偿。

DOI:
10.1039/b004528o
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发表时间:
2000
期刊:
The Analyst
影响因子:
--
通讯作者:
Zellers,ET
Zellers,ET
中科院分区:
--
文献类型:
--
作者:
Park,J;Zellers,ET

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Accounting for changes in temperature and ambient humidity is critical to the development of practical field vapor-monitoring instrumentation employing microfabricated sensor arrays. In this study, responses to six organic vapors were collected from two prototype field instruments over a range of ambient temperatures and relative humidities (RH). Each instrument contains an array of three unthermostated polymer-coated surface acoustic wave (SAW) resonators, a thermally desorbed adsorbent preconcentrator bed, a reversible pump and a small scrubber cartridge. Negligible changes in the vapor sensitivities with atmospheric RH were observed owing, in large part, to the temporal separation of co-adsorbed water from the organic vapor analytes upon thermal desorption of preconcentrated air samples. As a result, calibrations performed at one RH level could be used to determine vapors at any other RH without corrections using standard pattern recognition methods. Negative exponential temperature dependences that agreed reasonably well with those predicted from theory were observed for many of the vapor–sensor combinations. It was possible to select a subset of sensors with structurally diverse polymer coatings whose sensitivities to all six test vapors and selected binary vapor mixtures had similar temperature dependences. Thus, vapor recognition could be rendered independent of temperature and vapor quantification could be corrected for temperature with sufficient accuracy for most applications. The results indicate that active temperature control is not necessary and that temperature and RH compensation is achievable with a relatively simple microsensor system.
采用微传感器阵列分析呼出气中有机蒸气的原型仪器。
DOI: 10.1080/15428119691014189
发表时间: 1996
期刊: American Industrial Hygiene Association journal
影响因子: --
作者:
W. Groves;E. Zellers
通讯作者: E. Zellers
使用聚合物涂层表面声波传感器阵列分析有机蒸气混合物的最佳涂层选择。
DOI: 10.1021/ac00102a012
发表时间: 1995
影响因子: 7.4
作者:
Zellers,ET;Batterman,SA;Han,M;Patrash,SJ
通讯作者: Patrash,SJ
DOI: 10.1016/s0925-4005(99)00381-0
发表时间: 2000-02-25
影响因子: 8.4
作者:
Cai, QY;Park, J;Zellers, ET
通讯作者: Zellers, ET
用于选择性测量多种有机蒸气的个人监测仪器。
DOI: 10.1080/15298660008984528
发表时间: 2000
期刊: AIHAJ : a journal for the science of occupational and environmental health and safety
影响因子: --
作者:
Park,J;Zhang,GZ;Zellers,ET
通讯作者: Zellers,ET
DOI: 10.1021/ac9603643
发表时间: 1996-07
影响因子: 7.4
作者:
E. Zellers;Mingwei Han
通讯作者: E. Zellers;Mingwei Han