Emergence of a Cubic Phase Stabilized by Intermetallic Charge Transfer in (1-x)PbVO3-xBiCoO3 Solid Solutions
Emergence of a Cubic Phase Stabilized by Intermetallic Charge Transfer in (1-x)PbVO3-xBiCoO3 Solid Solutions
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DOI：
10.1021/acs.chemmater.0c01934
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发表时间：
2020-08-25
影响因子：
8.6
通讯作者：
Kimura, Hiroyuki
中科院分区：
文献类型：
--
作者：
Yamamoto, Hajime;Toda, Kaoru;Kimura, Hiroyuki
在这项研究中，报道了巨四方（GT）钙钛矿型PbVO3和BiCoO3之间的固溶体（即（1 - x）PbVO3-xBiCoO（3））的晶体结构演变。采用高压高温方法成功合成了全比例固溶体。在 0.4 处观察到立方相区域
In this study, the crystal structure evolution of solid solutions between giant-tetragonal (GT) perovskite-type PbVO3 and BiCoO3, namely, (1 - x)PbVO3-xBiCoO(3), is reported. The all-proportional solid solutions are successfully synthesized using a high-pressure and high-temperature method. A region of cubic phase is observed in the 0.4