Nickel-Catalyzed Cross-Coupling of Non-activated and Functionalized Alkyl Halides with Alkyl Grignard Reagents

Nickel-Catalyzed Cross-Coupling of Non-activated and Functionalized Alkyl Halides with Alkyl Grignard Reagents
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DOI:
10.1002/anie.200806138
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发表时间:
2009-01-01
影响因子:
16.6
通讯作者:
Hu, Xile
Hu, Xile
中科院分区:
化学1区
文献类型:
--
作者:
Vechorkin, Oleg;Hu, Xile

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标题反应是通过使用分离的 NiIII 络合物 (1) 实现的。该催化作用可耐受多种重要官能团,这些官能团在交叉偶联反应中通常与格氏试剂不相容。
The title reaction is realized by using an isolated NiII complex (1). The catalysis tolerates a wide range of important functional groups that are often incompatible with Grignard reagents in cross-coupling reactions.