Photoredox Activation and Anion Binding Catalysis in the Dual Catalytic Enantioselective Synthesis of β-Amino Esters.
Photoredox Activation and Anion Binding Catalysis in the Dual Catalytic Enantioselective Synthesis of β-Amino Esters.
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DOI：
10.1039/c3sc52265b
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发表时间：
2014-01
期刊：
影响因子：
8.4
通讯作者：
Stephenson CR
中科院分区：
文献类型：
--
作者：
Bergonzini G;Schindler CS;Wallentin CJ;Jacobsen EN;Stephenson CR
四氢异喹啉衍生物的对映选择性氧化C-H功能化是通过光氧化还原和不对称阴离子结合催化的合并实现的。这两种不同的催化概念的结合引入了氧化光催化中不对称转化的潜在通用方法。
The enantioselective oxidative C-H functionalization of tetrahydroisoquinoline derivatives is achieved through the merger of photoredox and asymmetric anion-binding catalysis. This combination of two distinct catalysis concepts introduces a potentially general approach to asymmetric transformations in oxidative photocatalysis.