AMINO-ACID N-DIMETHYLAMINOMETHYLENE ALKYL ESTERS - NEW DERIVATIVES FOR GC AND GC-MS STUDIES

AMINO-ACID N-DIMETHYLAMINOMETHYLENE ALKYL ESTERS - NEW DERIVATIVES FOR GC AND GC-MS STUDIES
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DOI:
10.1080/00032717208062117
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发表时间:
1972-01-01
期刊:
影响因子:
2
通讯作者:
HORNING, EC
HORNING, EC
中科院分区:
化学4区
文献类型:
--
作者:
THENOT, JP;HORNING, EC

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二甲基甲酰胺二烷基缩醛与氨基酸的羧基和氨基反应形成N-二甲基氨基亚甲基烷基酯(N-DMAM-烷基酯)衍生物。在100[ddot]C下观察到完全和快速的反应。在这些条件下,羟基不反应。
Dimethylformamide dialkylacetals react both with carboxylic and amino groups of amino acids to form N-dimethylaminomethylene alkyl ester (N-DMAM-alkyl ester) derivatives. Complete and rapid reaction was observed at 100[ddot]C. Under these conditions, hydroxyl groups did not react.