BASE-CATALYZED ANOMERIZATION OF BETA-5-FORMYLURIDINE - CRYSTAL AND MOLECULAR-STRUCTURE OF ALPHA-5-FORMYLURIDINE
BASE-CATALYZED ANOMERIZATION OF BETA-5-FORMYLURIDINE - CRYSTAL AND MOLECULAR-STRUCTURE OF ALPHA-5-FORMYLURIDINE
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DOI：
10.1093/nar/3.7.1791
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发表时间：
1976-01-01
影响因子：
14.9
通讯作者：
SAENGER, W
中科院分区：
文献类型：
--
作者：
ARMSTRONG, VW;DATTAGUPTA, JK;SAENGER, W
在用强碱处理时，β-5-甲酰基尿苷发生端基异构化，得到α-和β-端基异构体的混合物。用分级重结晶法分离了端基异构体，并用X射线衍射法确定了α-端基异构体的绝对构型。
On treatment with strong base β-5-formyluridine undergoes an anomerisation to give a mixture of the α- and β-anomers. The anomers have been separated by fractional recrystallisation and the absolute configuration of the α-anomer has been determined by X-ray analysis.