Incorporation of square-planar Pd2+ in fluorite CeO2: hydrothermal preparation, local structure, redox properties and stability

Incorporation of square-planar Pd2+ in fluorite CeO2: hydrothermal preparation, local structure, redox properties and stability
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DOI:
10.1039/c5ta02007g
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发表时间:
2015-01-01
影响因子:
11.9
通讯作者:
Walton, Richard I.
Walton, Richard I.
中科院分区:
材料科学2区
文献类型:
--
作者:
Hiley, Craig I.;Fisher, Janet M.;Walton, Richard I.

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研究了含Pd 2+的二氧化铈在240 ℃下的直接水热结晶,以研究贵金属掺杂剂可以引入立方萤石晶格的程度。组成为Ce 1-xPdxO 2-δ的样品,其中0
The direct hydrothermal crystallisation at 240 degrees C of Pd2+-containing ceria is investigated to study the extent to which precious metal dopants may be introduced into the cubic fluorite lattice. Samples of composition Ce1-xPdxO2-delta, where 0