Synthesis and Structure of a Ferrocenylsilane-Bridged Bisphosphine
Synthesis and Structure of a Ferrocenylsilane-Bridged Bisphosphine
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DOI：
10.3390/inorganics10020022
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发表时间：
2022-02
期刊：
影响因子：
2.9
通讯作者：
T. Sasamori;H. Ueno;Shogo Morisako
中科院分区：
文献类型：
--
作者：
T. Sasamori;H. Ueno;Shogo Morisako
合成了双二茂铁基硅烷桥联的双膦，即由双(1'-二环己基膦基-1-二茂铁基)二甲氧基硅烷桥联的双膦，并进行了结构表征。通过循环伏安法和微分脉冲伏安法检查其氧化还原行为，揭示了两步氧化过程。
A bisferrocenylsilane-bridged bisphosphine, i.e., a bisphosphine bridged by bis(1’-dicyclohexylphosphino-1-ferrocenyl)dimethoxysilane, was synthesized and structurally characterized. Its redox behavior was examined by cyclic voltammetry and differential pulse voltammetry, which revealed two-step oxidation processes.