Recent advances in interfacial engineering of perovskite solar cells

Recent advances in interfacial engineering of perovskite solar cells
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钙钛矿太阳能电池界面工程的最新进展

DOI:
10.1088/1361-6463/aa7cb0
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发表时间:
2017-08
影响因子:
3.4
通讯作者:
Lin Zhiqun
Lin Zhiqun
中科院分区:
物理与天体物理3区
文献类型:
--
作者:
Ye Meidan;He Chunfeng;Iocozzia James;Liu Xueqin;Cui Xun;Meng Xiangtong;Rager Matthew;Hong Xiaodan;Liu Xiangyang;Lin Zhiqun

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由于最近的发展,有机金属卤化物钙钛矿太阳能电池(PSCs)因其令人印象深刻的光伏性能和简单的器件制造工艺而引起了人们的极大兴趣,具有商业应用的潜力。PSCs的功率转换效率(PCE)已从2009年甲基铵卤化铅敏化液体太阳能电池CH3NH3PbX3(X  =  Cl,BrI)的3.8%飙升至2016年全固态太阳能电池的22%以上。在过去的几年中,致力于以更高的性能实现PSC。本文综述了近年来PSCs界面工程的研究进展。PSCs界面工程的具体策略分为两类:(1)溶剂处理和添加剂,以提高钙钛矿膜的捕光能力;(2)在有源层之间的界面上加入各种功能材料(如电子传输层、钙钛矿层和空穴传输层)。本文旨在全面综述PSCs的界面工程策略,包括增强光捕获、改进电荷分离和传输、改善器件稳定性和消除光电流滞后。
Due to recent developments, organometallic halide perovskite solar cells (PSCs) have attracted even greater interest owing to their impressive photovoltaic properties and simple device manufacturing processes with the potential for commercial applications. The power conversion efficiencies (PCEs) of PSCs have surged from 3.8% for methyl ammonium lead halide-sensitized liquid solar cells, CH3NH3PbX3 (X  =  Cl, Br, I), in 2009, to more than 22% for all-solid-state solar cells in 2016. Over the past few years, significant effort has been dedicated to realizing PSCs with even higher performance. In this review, recent advances in the interfacial engineering of PSCs are addressed. The specific strategies for the interfacial engineering of PSCs fall into two categories: (1) solvent treatment and additives to improve the light-harvesting capabilities of perovskite films, and (2) the incorporation of various functional materials at the interfaces between the active layers (e.g. electron transporting layer, perovskite layer, and hole transporting layer). This review aims to provide a comprehensive overview of strategies for the interfacial engineering of PSCs with potential benefits including enhanced light harvesting, improved charge separation and transport, improved device stability, and elimination of photocurrent hysteresis.
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