Gold(I)-catalyzed stereoselective formation of functionalized 2,5-dihydrofurans.
Gold(I)-catalyzed stereoselective formation of functionalized 2,5-dihydrofurans.
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DOI：
10.1002/chin.200636104
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发表时间：
2006-03
期刊：
影响因子：
5.2
通讯作者：
A. Buzas;F. Istrate;F. Gagosz
中科院分区：
文献类型：
--
作者：
A. Buzas;F. Istrate;F. Gagosz
[反应：见正文]描述了一项关于金(I)催化丁炔二醇苯甲酸酯重排生成功能化2，5-二氢呋喃的研究。温和的反应条件允许通过两个金(I)催化的异构化步骤高效、快速地立体选择性地合成各种2，5-二氢呋喃。
[reaction: see text] A study concerning the gold(I)-catalyzed rearrangement of butynediol monobenzoates into functionalized 2,5-dihydrofurans is described. The mild reaction conditions employed allow the efficient and rapid stereoselective synthesis of a variety of 2,5-dihydrofurans via a sequence of two gold(I)-catalyzed isomerization steps.