Recent Progress in Crystalline Borates with Edge-Sharing BO(4) Tetrahedra.
Recent Progress in Crystalline Borates with Edge-Sharing BO(4) Tetrahedra.
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DOI：
10.3390/molecules28135068
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发表时间：
2023-06-28
期刊：
影响因子：
4.6
通讯作者：
Cheng, Jian-Wen
中科院分区：
文献类型：
--
作者：
Li, Jing-Jing;Chen, Wei-Feng;Lan, You-Zhao;Cheng, Jian-Wen
晶体硼酸盐因其结构多样、用途广泛而受到广泛关注。长期以来，共享角的 B-O 单元被认为是硼酸盐结构化学的基本规则。高压合成的Dy4B6O15是第一个具有共边[BO4]四面体的硼酸化合物，而KZnB3O6是第一个具有共边[BO4]四面体的常压硼酸盐。共边连接模式极大地丰富了硼酸盐的结构化学，并有望在未来拓展新的应用。在这篇综述中，我们总结了具有共享边缘的[BO4]四面体晶体硼酸盐的最新进展。我们讨论了这些共边硼酸盐的合成、基本构建模块、结构特征和可能的应用。最后，我们还讨论了该领域的未来前景。
Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B–O unit is considered a basic rule in borate structural chemistry. The Dy4B6O15 synthesized under high-pressure is the first oxoborate with edge-sharing [BO4] tetrahedra, while the KZnB3O6 is the first ambient pressure borate with the edge-sharing [BO4] tetrahedra. The edge-sharing connection modes greatly enrich the structural chemistry of borates and are expected to expand new applications in the future. In this review, we summarize the recent progress in crystalline borates with edge-sharing [BO4] tetrahedra. We discuss the synthesis, fundamental building blocks, structural features, and possible applications of these edge-sharing borates. Finally, we also discuss the future perspectives in this field.
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