The oxorhenium(VII)-catalyzed direct condensation of phosphoric acid with an alcohol

The oxorhenium(VII)-catalyzed direct condensation of phosphoric acid with an alcohol
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DOI:
10.1002/anie.200604333
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发表时间:
2007-01-01
影响因子:
16.6
通讯作者:
Ishihara, Kazuaki
Ishihara, Kazuaki
中科院分区:
化学1区
文献类型:
--
作者:
Sakakura, Akira;Katsukawa, Mikimoto;Ishihara, Kazuaki

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(化学方程式)一起来吧...关于Re:氧合铼-(VII)络合物催化磷酸与醇的直接缩合以选择性地得到2-100-mmol规模的相应磷酸单酯(参见方案)。该方法对于磷酸单酯的重要工业合成是有用的。
(Chemical Equation Presented) Come together... over Re: Oxorhenium-(VII) complexes catalyze the direct condensation of phosphoric acid with an alcohol to selectively give the corresponding phosphoric acid monoester on a 2-100-mmol scale (see scheme). This method should be useful for the industrially important synthesis of phosphoric acid monoesters.